Resistance to biogenic sulphuric acid corrosion of polymer-modified mortars
The use of polymer-modified mortar and concrete (PMM and PMC) is investigated to improve the durability of concrete sewer pipes. The aim of the research is to ameliorate the resistance of concrete to biogenic sulphuric acid attack through polymer modification. Prior to the durability tests, experimental research is carried out to reveal the influence of polymer modification on the physical and mechanical properties of mortar and concrete. The results of this research are presented in this paper. Due to the interaction of the cement hydrates and the polymer particles or film, an interpenetrating network originates in which the aggregates are embedded. The density, porosity and location of the polymer film depend on the type of polymer emulsion and on its minimum film-forming temperature (MFT). If air entrainment is restricted, an increased flexural strength is measured. Scanning electron microscope (SEM) analyses reveal the presence of polymer film and cement hydrates in the mortar. The polymer film causes a retardation of the cement hydration as well as a restriction of crystal growth.